[Disulfanediylbis(ferrocenylthiophosphinato)-κ2 O,O]titanocene tetrahydrofuran trisolvate
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چکیده
The title compound, [Fe(2)Ti(C(5)H(5))(4))(C(10)H(8)O(2)P(2)S(4))]·3C(4)H(8)O, contains a central seven-membered TiO(2)P(2)S(2) ring with a very similar geometry compared to the derivative showing anisyl instead of ferrocenyl substituents, the Ti-O distance being marginally longer for the anisyl derivative. Two tetra-hydro-furan solvent mol-ecules are each disordered on a twofold axis.
منابع مشابه
{μ-1,2-Bis[bis(4-methoxyphenyl)phosphanyl]-1,2-dimethylhydrazine-κ2 P:P′}bis[chloridogold(I)] tetrahydrofuran disolvate
The title compound, [Au(2)Cl(2)(C(30)H(34)N(2)O(4)P(2))]·2C(4)H(8)O, is formed from a bidentate phosphine ligand complexed to two almost linearly coordinated gold(I) atoms [P-Au-Cl = 175.68 (3) Å]. The nuclei are 3.122 (2) Å apart. The mol-ecule exhibits a twofold rotation axis.
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The structure of the title compound, [MnCl(2)(C(5)H(10)O(2))(2)], was solved from low-temperature data collected at 100 (2) K. The asymmetric unit contains one half-mol-ecule with the Mn(II) ion located on a twofold axis. A distorted octa-hedral environment around the Mn atom is formed by two ether and two hydroxyl O atoms of two 2-(hydroxy-methyl)tetra-hydro-furan ligands, and by two chloride ...
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The title compound, [Au(2)Cl(2)(C(32)H(38)N(2)O(4)P(2))]·2C(4)H(8)O, is formed from a bidentate phosphine ligand complexed to two linear gold(I) nuclei [P-Au-Cl = 175.98 (3)°]. The nuclei are 3.1414 (2) Å apart. The mol-ecule exhibits a twofold symmetry axis. Stacks of the compound are formed through inter-molecular C-H⋯Cl inter-actions, while the tetra-hydro-furan (THF) solvate is further atta...
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In the crystal structure of the title compound, [Cr(3)(C(2)Cl(3)O(2))(7)O(H(2)O)(2)]·3CH(3)CN, the trinuclear [Cr(3)O(H(2)O)(2)(Cl(3)CCO(2))(7)] mol-ecule has an oxide O atom that is connected to one monodentate trichloro-acetate-coordinated and two water-coordinated Cr(III) atoms, the three metal atoms forming the points of an equilateral triangle. Each of the six remaining carboxyl-ate groups...
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